Conformation of a Rare Nucleoside in the Anti-Calculations for 2 ’-0-Methyl Cytidine Codon Loop of tRNAs : Potential Energy
Steve D Stellman
Brian E. Hingerty
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8 Figures and Tables
Fig. 1. Structure, numbering convention, and conformational angles for 2’-O-methyl cytidine.
Fig. 2. Energy, Erib, of ribose ring as a function of pseudorotation coordinate P. Major puckering conformations are symbolically noted.
Fig. 3. Histograms of frequency of observed angles for all conformations having energies of 7.0 kcal/mole or less.
Fig. 4. Correlation map of sugar puckering, P, with methoxy angle mi: (01, first thirteen minima; (O), other minima less than 7 kcal/mole.
Fig. 5 ( continued)
TABLE I1 Thirteen Lowest Minimum Energy Conformations Calculated for 2'-O-Methyl Cytidine
TABLE IV Comparison of Predicted and Observed Conformations of 2’-O-Methyl Cytidine ______ Dihedral angle, deg
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